Characters that were villains but for some reason or another became heroes (or anti-heroes in the majority of cases)
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A
- A-Train
- Aarbron
- Accelerator
- Adeleine
- Akame
- Alex DeLarge
- Alice Angel
- Alice Gehabich
- Alister Azimuth
- Ambush Bug
- Anakin Skywalker
- Android 16
- Android 17
- Android 21
- Angel (King of Fighters)
- Anguirus
- Annie Leonhardt
- Ant-Man (Scott Lang)
- Anti-Pops
- Aquarius
- Asgore Dreemurr
- Ashi
- Asriel Dreemurr
- Atrocitus
- Axel/Lea
- Azrael (DC Comics)
B
C
D
- Dabura
- Dark Mephisto
- Dark Pit
- Darkrai
- Darth Vader
- Deadshot
- Decapre
- Dian
- Diana Cavendish
- Diane Foxington
- Diego (Ice Age)
- Diego Brando
- Dimaria Yesta
- Dinobot
- Discord
- Donkey Kong
- Doppelganger (Scribblenauts)
- Doubutsu Gattai Tousai Zyuoh
- Dr. Heinz Doofenshmirtz
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- Dragonzord
- Dusknoir (Mystery Dungeon)
E
F
G
H
J
K